RTP Crystal
RbTiOPO4(RTP) crystal is currently the most commonly used type of practical electro-optic crystals with high frequency repetition, high power and narrow pulse width laser Q switching. RTP electro-optical devices are not only used in laser micromachining and laser ranging, but also in major scientific exploration projects because of their excellent comprehensive performance.
RbTiOPO4(RTP)—a crystal with large electro-optical coefficient, high photoresist damage threshold and stable physical and chemical properties
The growth temperature ranges from 950 °C to 800 °C and the growth period is usually between 45 and 60 days.As RTP is transparent from 0.4 to 3.5 μm, it can be used in multiple types of laser such as Er:YAG laser at 2.94 μm with fairly good efficiency. Bulk absorption measurements at 1.064 μm range from 50 to 150 ppm using Photothermal Common Path Interferometer.
Parameter
| Chemical formula | RbTiOPO4 |
| Crystal structure | Orthorhombic |
| Point group | mm2 |
| Lattice parameters, Å | a 12.96 |
| b 10.56 | |
| c 6.49 | |
| Density, g.cm-3 | 3.6 |
| Resistivity (20°C, 20% Humidity), Ohm.cm | 1012 |
| Aperture, mm2 | from 2×2 to 9×9 |
| Length, mm | up to 10 |
| Dimension tolerance | ±0.1 mm |
| Flatness | <l/8 @633 nm |
| Surface quality | Scratch/Dig 10/5 |
| Parallelism | better than 30 arc sec |
| Perpendicularity | better than 30 arc min |
| Angle tolerance | △q < 0.5°, △f < 0.5° |
| Coating | AR coatings |
| Clear aperture | >90% central area |
| Transmitting wavefront distortion | less than l/8 @ 633 nm Dimension |
| Melting Point | ~ 1000 °C |
| Ferroeletric transition temperature | ~810 °C |
| Mohs Hardness | ~5 |
| Thermal Expansion Coefficients, /°C | a1=1.01×10-5, a2=1.37×10-5, a3=-4.17×10-6 |
| Hygroscopic Susceptibility | No |
| Ionic conductivity (room temperature, 10 kHz) | 10-8 S/cm |
| Average refractive index | 1.8 | |
| Transparency range, μm | 0.35 → 4.5 | |
| Residual Absorption (PCI) at 1064 nm | <250 ppm/cm | |
| Electro-optical constants (@ 633 nm, 1 kHz), pm. V-1 | r13 | 10.9 |
| r23 | 15 | |
| r33 | 33 | |
| Dielectric constant | εeff=13 | |
| High damage threshold | >15 J/cm2 at 10 Hz,10 ns at 1064 nm performed on coated crystals of 10 mm long |
| Low operating voltage | 1300 V for Y-cut and 1600 V for X-cut at 1064 nm applied to a crystal pair of 4×4 mm² for the aperture and 2×10 mm for the length |
| Low bulk absorption | <250 ppm/cm at 1064 nm |
- Wide transparency range
- Stable mechanical and chemical properties
- High damage threshold
- Small volume
- Not easy to deliquesce
- High temperature stability
- Low half-wave voltage
- Suitable for high-frequency operation
Electro-Optic Modulator
High repetition rate (≥100 kHz) operation can be achieved by Q-switching, especially actively Q-switching, due to its stable pulse energy and low temporal jitter at high repetition rates. Active Q-switching mainly contains two commonly used Q-switch modes, acousto-optic (AO) Q-switch and electro-optic (EO) Q-switch. The AO Q-switched laser has the feature of high repetition rate (normally can reach 200 kHz), but it is limited in many fields due to its tendency to produce long pulse (typically several tens to one hundred nano-seconds). Compared to AO Q-switch, EO Q-switch can overcome the shortcomings of AO Q-switch, and get stable short pulses due to its fast loss change. But the EO Q-switch requires very high voltage driver; this leads the high pulse repetition rate is difficult to obtain. In recent years, with the development of new types of electro-optic crystals RTP, the repetition rates of EO Q-switched solid state lasers have been improved significantly.
[Ref] High repetition rate 880 nm diode-directly-pumped electro-optic Q-switched Nd:GdVO4 laser with a double-crystal RTP electro-optic modulator
| High repetition rate 880 nm diode-directly-pumped electro-optic Q-switched Nd:GdVO4 laser with a double-crystal RTP electro-optic modulator |
| RTP Q-switched single-longitudinal-mode Nd:YAG laser with a twisted-mode cavity |
| Study of RTP crystal used as Electro-Optic modulator |
| Efficient RTP-based OPO intracavity pumped by an acousto-optic Q-switched Nd:YVO4 laser |
| Characterization of RbTiOPO4 Crystal for Electro-Optic and Non-Linear Applications |
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| Nonlinear optical properties ofthe flux grown RbTiOPO4 crystal |
| Stimulated polariton scattering in an intracavity RbTiOPO4 crystal generating frequency-tunable THz output |
| Crystal growth and refined Sellmeier equations over the complete transparency range of RbTiOPO4 |
| Blue SHG Enhancement by Silver Nanocubes Photochemically Prepared on a RbTiOPO4 Ferroelectric Crystal |
| Crystallization Region, Crystal Growth, and Characterization of Rubidium Titanyl Phosphate Codoped with Niobium and Lanthanide Ions |
| Crystal Growth of RbTiOPO4:Nb: A New Nonlinear Optical Host for Rare Earth Doping |
| RTP Q-Switched 2—Micron Tm:YAG Laser |
| Periodic poling of RbTiOPO 4 for quasi-phase matched blue light generation |
| Characterization of RbTiOPO4 Crystal for Non-Linear and Electro-Optic Applications |
| Crystal Structure of the Replication Terminator Protein from B. subtilis at 2.6 A |
| The inelastic light Scattering of RbTiOPO4 single crystal |
| Spectroscopic and second harmonic generation properties of a new crystal: Yb-doped RbTiOPO4 |
| Growth of RbTiOPO4 single crystals from phosphate systems |
| Laser damage investigation in nonlinear crystals: Study of KTiOPO4 (KTP) and RbTiOPO4 (RTP) crystals |
| Femtosecond-Laser Microstructuring of Ribs on Active (Yb,Nb):RTP/RTP Planar Waveguides |
| Switching Dielectric Constant Near Room Temperature in a Molecular Crystal |
| Crystal Structures of RbTiOAsO4, KTiO(Po.ss,Aso.4z)O4, RbTiOPO4 and (Rbo.46s,Ko.s3s)TiOPO4, and Analysis of Pseudosymmetry in Crystals of the KTiOPO4 Family |
| Broad emission band of Yb3+ in the nonlinear Nb:RbTiOPO4 crystal: origin and applications |
| Dissymmetrization in X-Irradiated RbTiOPO4 Crystal |
| Nanosecond laser induced damage in RbTiOPO4: The missing influence of crystal quality |
| Ferroelectric phase transition temperatures of self-flux-grown RbTiOPO4 crystals |
| Progress in crystal growth and characterisation of rare-earth doped non-linear KTP crystals for laser applications |
| Crystal growth and characterization of KTIOPO4 isomorphs from the self-fluxes |
| ELASTIC COEFFICIENTS OP KTIOPO4, RbTiOP04, TITIOPO4 GRYSTALS DETERMINED PROM MANDELSTAMM-BRILLOUIN LIGHT SCATTERING SPECTRA |
| RTP QSwitched 2 µm Tm,Ho:GdVO4 Laser |
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